(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)diiodidocadmium
نویسندگان
چکیده
In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol-ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra-hedral geometry. Inversion-related mol-ecules inter-act along the c-axis direction by π-π stacking inter-actions between the phenanthroline ring systems, with centroid-centroid distances of 3.707 (9) and 3.597 (10) Å.
منابع مشابه
Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)zinc
The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular π-π stacking between adjacent ph...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011